Rapid spontaneous alloying between Pd nanocubes and Ag nanoparticles in aqueous solution at ambient temperature.

نویسندگان

  • Masaharu Tsuji
  • Chihiro Shiraishi
  • Masashi Hattori
  • Atsuhiko Yajima
  • Masahito Mitarai
  • Keiko Uto
  • Koichi Takemura
  • Yukinori Nakashima
چکیده

Rapid spontaneous alloying between Pd nanocubes and spherical or triangular Ag nanoparticles was studied in an aqueous solution at ambient temperature using transmission electron microscopy (TEM), TEM-energy-dispersed X-ray spectroscopy (EDS), XRD, and UV-Vis spectroscopy of product particles. The results show that alloying occurs between Ag particles and Pd cubes and finishes within a few seconds, preserving the cubic shape with maximum Ag content of approximately 22%.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kinetically controlled synthesis of large-scale morphology-tailored silver nanostructures at low temperature.

Ag nanostructures are widely used in catalysis, energy conversion and chemical sensing. Morphology-tailored synthesis of Ag nanostructures is critical to tune physical and chemical properties. In this study, we develop a method for synthesizing the morphology-tailored Ag nanostructures in aqueous solution at a low temperature (45 °C). With the use of AgCl nanoparticles as the precursor, the gro...

متن کامل

Synthesis of silver nanoparticles using leaves aqueous extract of Nasturtium Officinale (NO) and its antibacterial activity

Biogenic reduction of silver ion to base metal is quite rapid, readily conducted at room temperature and pressure, and easily scaled up. Synthesis mediated by plant extracts is environmentally benign. The objective of this study was to synthesis of silver nanoparticles (Ag-NPs) using leaves aqueous extract of Nasturtium Officinale R. Br. (NO) and its antibacterial activity. X-ray diffraction (X...

متن کامل

Synthesis of Copper Nanoparticles in Aqueous Ambient Using Dismutation Reaction

The present study has investigated the synthesis of copper nanoparticles via copper dismutation reaction in an aqueous solution and ambient conditions. Copper (II) chloride hydrate ( ), sodium oleate (SO), sodium chloride (NaCl) and ethylene diamine (EN) have been used as copper (I, II) ions source, surfactant, chloride ions supplier and ligand, respectively. Also, an amount of hydrochloric aci...

متن کامل

Adsorption of Methylene Blue from Aqueous Solutions by Silk Cocoon ‎

This study concerns the performance of cocoons spun by silk worms as a natural ‎adsorbent for removal of Methylene Blue (MB) from aqueous solutions. To study the adsorption ‎process, the effect of various parameters such as contact time, adsorbent dosage, dye initial ‎concentration, and pH of the solution were investigated. According to the experiments, the kinetic ‎data were best described by ...

متن کامل

Aqueous route to facile, efficient and functional silica coating of metal nanoparticles at room temperature.

Various metal (Ag, Au, and Pt)@thiol-functionalized silica (SiO2-SH) nanoparticles (NPs) are successfully prepared at room temperature by a facile, efficient, functional, universal and scalable coating process in alcohol-free aqueous solution using pre-hydrolyzed 3-(mercaptopropyl)trimethoxysilane (MPTMS). The controlled pre-hydrolysis of the silane precursor in water and the consecutive conden...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Chemical communications

دوره 49 93  شماره 

صفحات  -

تاریخ انتشار 2013